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Formation and relaxation of RbHe exciplexes on He nanodroplets studied by femtosecond pump and picosecond probe
1Physikalisches Institut, Universität Freiburg, 79104 Freiburg, Germany.
Abstract:
Vibrationally resolved photoionization spectra of RbHe exciplexes forming on He nanodroplets are recorded using femtosecond pump-probe spectroscopy with amplitude-shaped probe pulses. The time-evolution of the spectra reveals an exciplex formation time ~10 ps followed by vibrational relaxation extending up to ≳ 1 ns. This points to an indirect, time-delayed desorption process of RbHe off the He surface.
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