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An improved thermodynamic perturbation theory for square-well m-point model of the patchy colloids
Y V Kalyuzhnyi1, S P Hlushak, P T Cummings
1Institute for Condensed Matter Physics, Svientsitskoho 1, 79011 Lviv, Ukraine.
Abstract:
We propose an improved version of Wertheim's first order thermodynamic perturbation theory for the square-well m-point model of patchy colloids. Our version of the theory takes into account changes in the free volume of the system due to bond formation. The new theory is a significant improvement, giving good agreement with Monte Carlo simulations of the model.
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