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Updated: May 15, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
06:35

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates

Published on: February 15, 2016

Binary complexes of ammonia with phenylacetylenes: a combined experimental and computational approach to explore

Arghya Dey1, Sohidul Islam Mondal, G Naresh Patwari

  • 1Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 40007, India.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|January 3, 2013
PubMed

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The basicity of aromatic amines is much weaker than that of aliphatic amines due to the involvement of the lone pair of electrons over the N atom in resonance with the aryl rings. Generally, the electron-donating ability of any substituents on the aryl ring of aromatic amines increases the basicity of the amine by increasing electron density, and hence the availability of lone pair on the nitrogen. On the other hand, electron-withdrawing functional groups on the aryl ring of amines decrease the...
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Basicity of Aliphatic Amines

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