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Updated: May 15, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Formation of a Ph2PCH(BH3)P(BH3)Ph2 ligand via formal 1,2-borane migration
Jens Langer1, Villö K Pálfi, Helmar Görls
1Institute of Inorganic and Analytical Chemistry, Friedrich-Schiller-University Jena, Humboldtstrasse 8, D-07743 Jena, Germany. j.langer@uni-jena.de
Abstract:
The transfer of the anionic Ph(2)P(BH(3))-CH-P(BH(3))Ph(2) ligand from potassium to barium results in the subsequent formation of a tetranuclear barium cluster which contains the hitherto unknown isomeric form Ph(2)P-CH(BH(3))-P(BH(3))Ph(2) of the ligand.
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