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MO Theory and Covalent Bonding02:40

MO Theory and Covalent Bonding

The molecular orbital theory describes the distribution of electrons in molecules in a manner similar to the distribution of electrons in atomic orbitals. The region of space in which a valence electron in a molecule is likely to be found is called a molecular orbital. Mathematically, the linear combination of atomic orbitals (LCAO) generates molecular orbitals. Combinations of in-phase atomic orbital wave functions result in regions with a high probability of electron density, while...
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Preparation of Diols and Pinacol Rearrangement01:57

Preparation of Diols and Pinacol Rearrangement

Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal diols or glycols. Under acidic conditions, vicinal diols undergo a specific reaction called pinacol rearrangement.
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.
Electronic Structure of Atoms02:28

Electronic Structure of Atoms


An atom comprises protons and neutrons, which are contained inside the dense, central core called the nucleus, with electrons present around the nucleus. Taking into account the wave–particle duality of electrons and the uncertainty in position around the nucleus, quantum mechanics provides a more accurate model for the atomic structure. It describes atomic orbitals as the regions around the nucleus where electrons of discrete energy exist, characterized by four quantum numbers:  n, l, ml, and...
Hückel's Rule Diagram of π MOs: Frost Circle01:08

Hückel's Rule Diagram of π MOs: Frost Circle

The Frost circle or the inscribed polygon method is a graphical method for determining the relative energies of π molecular orbitals (MOs) for planar, fully conjugated, and monocyclic compounds. This method was first described by A. A. Frost and Boris Musulin in 1953.
A Frost circle is constructed by drawing a polygon whose number of edges is equal to the number of carbons of the given cyclic system, with one of the vertices pointing down. Then, a circle is drawn enclosing the polygon so that...
Quantum Numbers02:43

Quantum Numbers

It is said that the energy of an electron in an atom is quantized; that is, it can be equal only to certain specific values and can jump from one energy level to another but not transition smoothly or stay between these levels.

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Related Experiment Video

Updated: May 15, 2026

Design and Validation of a Volumetric-extrusion Bioprinter for Bioprinting of Soluble Basement Membrane Extract for Translational Research
08:27

Design and Validation of a Volumetric-extrusion Bioprinter for Bioprinting of Soluble Basement Membrane Extract for Translational Research

Published on: March 28, 2025

LiNa(5)Mo(9)O(30).

Hamadi Hamza1, Ines Ennajeh, Mohamed Faouzi Zid

  • 1Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis ElManar, 2092 Manar II Tunis, Tunisia.

Acta Crystallographica. Section E, Structure Reports Online
|January 4, 2013
PubMed
Summary

Lithium penta-sodium nona-molybdate, LiNa(5)Mo(9)O(30), was synthesized. Its 3D framework, built from molybdenum oxide polyhedra, features tunnels housing sodium and lithium ions.

Area of Science:

  • Inorganic Chemistry
  • Solid-State Chemistry
  • Crystal Chemistry

Background:

  • Molybdenum oxide compounds exhibit diverse structural motifs.
  • Ternary alkali metal molybdates are of interest for their unique framework structures.

Purpose of the Study:

  • To synthesize and characterize a novel ternary molybdate, lithium penta-sodium nona-molybdate.
  • To elucidate the crystal structure and bonding of LiNa(5)Mo(9)O(30).

Main Methods:

  • Solid-state reaction synthesis.
  • Single-crystal X-ray diffraction analysis.

Main Results:

  • The compound LiNa(5)Mo(9)O(30) was successfully synthesized.
  • A 3D [Mo(9)O(30)](6-) framework composed of MoO(6) octahedra and MoO(5) bipyramids was identified.

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Syntheses, Crystallization, and Spectroscopic Characterization of 3,5-Lutidine N-Oxide Dehydrate
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Syntheses, Crystallization, and Spectroscopic Characterization of 3,5-Lutidine N-Oxide Dehydrate
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Syntheses, Crystallization, and Spectroscopic Characterization of 3,5-Lutidine N-Oxide Dehydrate

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  • Two intersecting tunnel systems within the framework accommodate Li(+) and Na(+) cations.
  • The crystal structure revealed a racemic twin with a specific twin ratio.
  • Conclusions:

    • The structure of lithium penta-sodium nona-molybdate presents a novel framework architecture.
    • The arrangement of cations within the tunnels provides insights into structure-property relationships in molybdenum oxides.
    • Comparative analysis with related alkali metal molybdates highlights structural diversity.