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7-Meth-oxy-indan-1-one.

Yuan Jay Chang1, Kew-Yu Chen

  • 1Department of Chemistry, Tung Hai University, 407 Taichung, Taiwan.

Acta Crystallographica. Section E, Structure Reports Online
|January 4, 2013
PubMed
Summary
This summary is machine-generated.

This study reveals the crystal structure of a C(10)H(10)O(2) compound. Molecules form layered structures through hydrogen bonds, further stabilized into a 3D network by weak interactions.

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Area of Science:

  • Crystallography
  • Supramolecular Chemistry
  • Organic Chemistry

Background:

  • Understanding molecular packing and intermolecular interactions is crucial in crystal engineering.
  • 1-Indanone derivatives are important scaffolds in medicinal chemistry and materials science.
  • Detailed structural analysis provides insights into solid-state properties and potential applications.

Purpose of the Study:

  • To elucidate the crystal structure of the title compound C(10)H(10)O(2).
  • To investigate the intermolecular interactions governing the solid-state architecture.
  • To characterize the hydrogen bonding and C-H⋯π interactions present in the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction analysis was employed to determine the molecular and crystal structure.
  • Analysis of intermolecular contacts, including hydrogen bonds and C-H⋯π interactions, was performed.
  • Geometric parameters and deviations from planarity were quantified.

Main Results:

  • The 1-indanone unit within the C(10)H(10)O(2) molecule exhibits near planarity.
  • Molecules are arranged in layers parallel to the ab plane, mediated by C-H⋯O hydrogen bonds.
  • Weak C-H⋯π interactions play a significant role in stabilizing the 2D layered structure and forming a 3D supramolecular network.

Conclusions:

  • The crystal structure of C(10)H(10)O(2) is characterized by a layered arrangement stabilized by hydrogen bonding.
  • C-H⋯π interactions are identified as key non-covalent forces contributing to the overall three-dimensional architecture.
  • This detailed structural understanding can inform the design of related organic materials with tailored properties.