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Updated: May 15, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
(2-{[2-(diphenyl-phosphino)phen-yl]thio}-phen-yl)diphenyl-phosphine sulfide
Angel Alvarez-Larena1, Francisco J Martinez-Cuevas, Teresa Flor
1Servicio Difracción Rayos X, Universidad Autónoma de Barcelona, 08193 Cerdanyola, Spain.
Abstract:
In the title compound, C(36)H(28)P(2)S(2), the dihedral angle between the central benzene rings is 66.95 (13)°. In the crystal, molecules are linked via C(ar)-H⋯π and π-π inter-actions [shortest centroid-centroid distance between benzene rings = 3.897 (2) Å].
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