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Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

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Mesoporous materials and electrochemistry.

Alain Walcarius¹

¹Laboratoire de Chimie Physique et Microbiologie pour l'Environnement, UMR 7564 CNRS - Université de Lorraine, 405 rue de Vandoeuvre, 54600 Villers-les-Nancy, France. alain.walcarius@lcpme.cnrs-nancy.fr

Chemical Society Reviews

|January 22, 2013

Summary

Ordered mesoporous materials offer unique properties for electrochemical devices. This review explores their characterization, synthesis, and applications in sensing and energy technologies.

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Area of Science:

Materials Science
Electrochemistry
Nanotechnology

Background:

Ordered mesoporous materials possess unique properties valuable for electrochemical applications.
These materials can be insulating, semiconducting, or conducting.

Purpose of the Study:

To review the intersection of electrochemistry and ordered mesoporous materials.
To cover characterization, synthesis, and applications of these materials.

Main Methods:

Electrochemical characterization of mesoporous material properties (charge/mass transfer).
Electro-assisted deposition for generating mesostructured solids.
Fabrication of electrodes using mesoporous materials.

Main Results:

Mesoporous materials have been successfully applied in electrochemical sensing, biosensing, and energy storage/conversion.
Both bulk composite and thin film configurations are utilized.
Diverse material types including silica, metal oxides, metals, and carbons are employed.

Conclusions:

Ordered mesoporous materials are versatile for electrochemical devices.
Further research can expand their utility in sensing and energy applications.