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Boron carbides as efficient, metal-free, visible-light-responsive photocatalysts

Jikai Liu1, Shuhao Wen, Yang Hou

  • 1Department of Chemistry, University of California, Riverside, CA 92521, USA.

Angewandte Chemie (International Ed. in English)
|January 29, 2013
PubMed
Abstract

No abstract available in PubMed .

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One of the convenient methods for the preparation of aldehydes and ketones is via hydration of alkynes. Hydroboration-oxidation of alkynes is an indirect hydration reaction in which an alkyne is treated with borane followed by oxidation with alkaline peroxide to form an enol that rapidly converts into an aldehyde or a ketone. Terminal alkynes form aldehydes, whereas internal alkynes give ketones as the final product.