Quantification of PAHs and chlorinated compounds by novel solid-phase microextraction based on the arrays of tin...

The results of an innovative study on a new and highly efficient stationary phase based on the SnO2 nanorods coating on fused silica have been reported in this paper. SnO2 nanorods have been grown on fused silica fibers using a hydrothermal process. The extraction properties of the fiber were investigated using headspace solid-phase microextraction (HS-SPME) mode coupled with gas chromatography-mass spectrometry detection for 1,4-dichloro-2-nitrobenzene, biphenyl, and acenaphthene. The effect of different variables on extraction efficiency was studied simultaneously using Box-Behnken method as experimental design. The variables of interest in the HS-SPME were salt effect, adsorption temperature, extraction, and desorption time. Under optimal conditions, the calibration curves were linear up to 10(2)-10(5) ng L(-1) (R(2) > 0.998) with detection limits of 10(-3), 10(-1), and 10 ng L(-1) for acenaphthene, biphenyl, and 1,4-dichloro-2-nitrobenzene, respectively. The relative standard deviations for single fiber and fiber to fiber were less than 9.8 and 12.5 %, respectively. The high stability of the SnO2 nanostructure coating is proved at relatively high temperatures (up to 300 °C) with a high extraction capacity and long lifespan (more than 100 times). By applying the proposed technique, promising recoveries (93-98 %) were obtained in the analysis of environmental water samples.