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Updated: May 14, 2026

Fabrication and Optimization of Type II Silicon Clathrate Films
Published on: October 14, 2025
An organosilicon cluster with an octasilacuneane core: a missing silicon cage motif
Shintaro Ishida1, Kyohei Otsuka, Yuki Toma
1Department of Chemistry and Chemical Biology, Graduate School of Engineering, Gunma University, Kiryu, Gunma 376-8515, Japan. sishida@m.tohoku.ac.jp
Abstract:
Cagey silicon: A silicon cluster, consisting of sixteen silicon atoms and composed of an octasilacuneane core (red, see picture) fused with cyclotetrasilanes (orange), was synthesized by reductive tetramerization of tetrachlorocyclotetrasilane. Analytical and theoretical studies reveal the unique structural and electronic features of this organosilicon cluster.
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