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Non-conservative Forces01:17

Non-conservative Forces

Non-conservative forces are dissipative forces such as friction or air resistance. These forces take energy away from a system as it progresses. Unlike conservative forces, non-conservative forces do not have potential energy associated with them. This is because the energy is lost to the system and cannot be turned into useful work later.
Also unlike their conservative counterparts, they are path-dependent; where the object starts and stops does matter. For example, a grinding wheel applies a...
Spin–Spin Coupling Constant: Overview01:08

Spin–Spin Coupling Constant: Overview

In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...
Electromagnetic Fields01:30

Electromagnetic Fields

Electric fields generated by static charges, often referred to as electrostatic fields, are characteristically different from electric fields created by time-varying magnetic fields. While the former is a conservative field, implying that no net work is done on a test charge if it goes around in a complete loop in the field, the latter is, by definition, not a conservative field; net work is done, and it is proportional to the rate of change of magnetic flux.
However, the observation of Gauss's...
Induced Electric Fields: Applications01:27

Induced Electric Fields: Applications

An important distinction exists between the electric field induced by a changing magnetic field and the electrostatic field produced by a fixed charge distribution. Specifically, the induced electric field is nonconservative because it does not work in moving a charge over a closed path. In contrast, the electrostatic field is conservative and does no net work over a closed path. Hence, electric potential can be associated with the electrostatic field but not the induced field. The following...
Conservation of Mass in Moving, Nondeforming Control Volume01:14

Conservation of Mass in Moving, Nondeforming Control Volume

Stormwater detention basins are essential in managing runoff during heavy rainfall, particularly in urban areas where impervious surfaces increase the risk of flooding. Understanding the conservation of mass in these systems allows engineers to optimize basin performance, balancing inflow, outflow, and water storage.
In the context of a detention basin, the conservation of mass states that the total mass of water entering the basin must equal the mass leaving the basin plus any accumulation of...
Electric Field of a Non Uniformly Charged Sphere01:22

Electric Field of a Non Uniformly Charged Sphere

Gauss's law states that the electric flux through any closed surface equals the net charge enclosed within the surface. This law is beneficial for determining the expressions for the electric field for a particular charge distribution if the electric flux is known.
Consider a non-uniformly charged sphere, for which the density of charge depends only on the distance from a point in space and not on the direction. Such a sphere has a spherically symmetrical charge distribution. Here, the electric...

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Updated: May 14, 2026

Lens-free Video Microscopy for the Dynamic and Quantitative Analysis of Adherent Cell Culture
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Kinetic cross coupling between nonconserved and conserved fields in phase field models.

Efim A Brener1, G Boussinot

  • 1Peter Grünberg Institut, Forschungszentrum Jülich, D-52425 Jülich, Germany.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|February 2, 2013
PubMed
Summary
This summary is machine-generated.

This study introduces a phase field model for alloy transformations, incorporating kinetic cross-coupling effects. The model accurately reduces to macroscopic free boundary problems, validated by simulations and discussing solute trapping relevance.

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Area of Science:

  • Materials Science
  • Computational Materials Science
  • Physical Chemistry

Background:

  • Phase field models are crucial for simulating materials transformations.
  • Understanding kinetic cross-coupling is vital for accurate alloy behavior prediction.
  • Macroscopic descriptions often simplify complex microstructural evolution.

Purpose of the Study:

  • To develop a phase field model for isothermal transformations in two-component alloys.
  • To incorporate Onsager kinetic cross-coupling between phase and concentration fields.
  • To reduce the phase field model to a macroscopic free boundary problem.

Main Methods:

  • Development of a phase field model including nonconserved and conserved fields.
  • Mathematical reduction of the phase field model to a macroscopic free boundary problem.
  • Validation through direct phase field simulations and comparison with the reduced model.

Main Results:

  • A novel phase field model for two-component alloys with Onsager kinetic cross-coupling is presented.
  • The general reduction to a macroscopic free boundary problem is derived.
  • Excellent agreement between the reduced model and direct simulations is demonstrated.

Conclusions:

  • The developed phase field model accurately captures alloy transformations with cross-coupling effects.
  • The reduction to macroscopic descriptions provides a simplified yet valid framework.
  • The model and its reduction are relevant for understanding phenomena like solute trapping.