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Related Concept Videos

Semiconductors01:22

Semiconductors

There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Fermi Level01:18

Fermi Level

The Fermi-Dirac function is represented by an S-shaped curve indicating the probability of an energy state being occupied by an electron at a given temperature. The Fermi level is the energy level at which there is a fifty percent chance of finding an electron, and it is positioned between the lower-energy valence band and the higher-energy conduction band.
At absolute zero temperature, electrons fill all energy states up to the Fermi level, leaving upper states empty. As the temperature rises,...
Types of Semiconductors01:20

Types of Semiconductors

Intrinsic semiconductors are highly pure materials with no impurities. At absolute zero, these semiconductors behave as perfect insulators because all the valence electrons are bound, and the conduction band is empty, disallowing electrical conduction. The Fermi level is a concept used to describe the probability of occupancy of energy levels by electrons at thermal equilibrium. In intrinsic semiconductors, the Fermi level is positioned at the midpoint of the energy gap at absolute zero. When...
Band Theory02:35

Band Theory

When two or more atoms come together to form a molecule, their atomic orbitals combine and molecular orbitals of distinct energies result. In a solid, there are a large number of atoms, and therefore a large number of atomic orbitals that may be combined into molecular orbitals. These groups of molecular orbitals are so closely placed together to form continuous regions of energies, known as the bands.
The energy difference between these bands is known as the band gap.
Conductor, Semiconductor,...
Debye–Huckel–Onsager Conductance Equation01:28

Debye–Huckel–Onsager Conductance Equation

The Debye-Hückel-Onsager equation is a cornerstone of physical chemistry, providing a method to determine the molar conductance (Λm) and molar conductance at infinite dilution (Λ°m) for uni-univalent electrolytes.Uni-univalent electrolytes are electrolytes that dissociate in solution to produce one cation with a +1 charge and one anion with a –1 charge per formula unit.This equation addresses two crucial phenomena: the asymmetry effect and the electrophoretic effect. According to this equation,...
Fermi Level Dynamics01:12

Fermi Level Dynamics

The vacuum level denotes the energy threshold required for an electron to escape from a material surface. It is usually positioned above the conduction band of a semiconductor and acts as a benchmark for comparing electron energies within various materials.
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
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Fabrication of Gate-tunable Graphene Devices for Scanning Tunneling Microscopy Studies with Coulomb Impurities
11:42

Fabrication of Gate-tunable Graphene Devices for Scanning Tunneling Microscopy Studies with Coulomb Impurities

Published on: July 24, 2015

Impurity state and variable range hopping conduction in graphene.

Sang-Zi Liang1, Jorge O Sofo

  • 1Department of Physics and Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.

Physical Review Letters
|February 2, 2013
PubMed
Summary
This summary is machine-generated.

Variable range hopping theory does not apply to covalently attached impurities in graphene. Impurity state wave function decay follows a power law, leading to conductivity dependent on temperature, aligning with experimental data.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Quantum Mechanics

Background:

  • Variable range hopping theory describes electron transport in disordered materials.
  • Exponential localization of impurity states is a key assumption in this theory.
  • Graphene with covalently attached impurities presents a different scenario.

Purpose of the Study:

  • To analyze impurity state localization in graphene with covalently attached impurities.
  • To determine the applicability of variable range hopping theory in this system.
  • To investigate the temperature dependence of conductivity.

Main Methods:

  • Nearest-neighbor, tight-binding model for adatom-graphene system.
  • Green's function perturbation methods.
  • Analysis of impurity state wave function decay.

Main Results:

  • Impurity state wave function amplitude decays as a power law.
  • Exponents of decay depend on sublattice, direction, and impurity species.
  • Conductivity exhibits a power-law dependence on temperature.

Conclusions:

  • Variable range hopping theory, as formulated for exponential localization, is not directly applicable.
  • The power-law decay of wave functions leads to a distinct temperature dependence of conductivity.
  • The findings are consistent with experimental observations in graphene systems.