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Related Concept Videos

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Experimental Methods for Trapping Ions Using Microfabricated Surface Ion Traps
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Fermi nesting between atomic wires with strong spin-orbit coupling.

C Tegenkamp1, D Lükermann, H Pfnür

  • 1Institut für Festkörperphysik, Leibniz Universität Hannover, Appelstraße 2, 30167 Hannover, Germany. tegenkamp@fkp.uni-hannover.de

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|February 2, 2013
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Atomic Pb wires on Si(557) exhibit a correlated spin and charge state due to superlattice effects. This leads to spin-polarized charge-density waves and significant Rashba splitting, impacting spin transport.

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Surface Science

Background:

  • Superlattice structures influence electronic properties.
  • Spin-orbit coupling is crucial for spin states.
  • Atomic wires offer unique electronic phenomena.

Purpose of the Study:

  • Investigate the electronic spin and charge state in atomic Pb wires on Si(557).
  • Explore the interplay of superlattice structure, band filling, and spin-orbit coupling.
  • Understand the resulting spin texture and charge-density waves.

Main Methods:

  • Spin- and angle-resolved photoemission spectroscopy (SARPES).
  • Fabrication of atomic Pb wires on a Si(557) surface.

Main Results:

  • Observed a highly correlated electronic spin and charge state.
  • Identified alternating and equidistant spin texture near the Fermi surface.
  • Demonstrated Fermi nesting leading to spin-polarized charge-density waves across wires.
  • Measured an extraordinary large Rashba splitting (Δk0=0.2 Å⁻¹).

Conclusions:

  • The findings fit models of spin-density waves in antiferromagnetic chain structures.
  • The results suggest implications for spin-polarized transport along the wires.