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Updated: May 14, 2026

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Near-infrared luminescence in TlCl:Bi crystal
V G Plotnichenko1, V O Sokolov, D V Philippovskiy
1Fiber Optics Research Center of the Russian Academy of Sciences, Moscow, Russia.
Abstract:
Experimental and theoretical studies of spectral properties of crystalline TlCl:Bi are performed. Two broad near-infrared luminescence bands with a lifetime of about 0.25 ms are observed: a strong band near 1.18 μm excited by 0.40, 0.45, 0.70, and 0.80 μm radiation and a weak band at ≳1.5 μm excited by 0.40 and 0.45 μm radiation. Computer modeling of Bi-related centers in TlCl lattice suggests that a Bi(+)…VCl(Cl)(-) center (Bi(+) in Tl site and a negatively charged Cl vacancy in the nearest anion site) is most likely responsible for the IR luminescence.
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