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Updated: May 14, 2026

Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Dispersion and anisotropy of thermo-optic coefficients in tetragonal GdVO4 and YVO4 laser host crystals
Pavel A Loiko1, Konstantin V Yumashev, Vladimir N Matrosov
1Center for Optical Materials and Technologies, Belarusian National Technical University, Minsk, Belarus.
Abstract:
A detailed experimental study of dispersion and anisotropy of thermo-optic coefficients dn/dT and thermal coefficients of the optical path W=dn/dT+(n-1)α is performed for tetragonal YVO(4) and GdVO(4) laser host crystals by a laser beam deviation method. It is supported by theoretical description of thermo-optic effects, taking into account the volumetric thermal expansion effect and the temperature dependence of electronic bandgap E(g). Linear thermal expansion coefficients α were also determined by a dilatometric technique. Thermo-optic dispersion formulas describing temperature variation of the refractive index and the thermal lens effect are derived for a wide spectral range of 0.4-2 μm. It allows us to estimate the values of E(g) and dE(g)/dT for the studied crystals. The influence of materials parameters and pumping conditions on thermal lens properties is discussed, revealing the significant impact of anisotropic and temperature-dependent thermal conductivity.
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