Related Experiment Video
Updated: May 14, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
Energy level alignment of cyclohexane on Rh(111) surfaces: the importance of interfacial dipole and final-state
Takanori Koitaya1, Kozo Mukai, Shinya Yoshimoto
1The Institute for Solid State Physics, The University of Tokyo, 5-1-5, Kashiwanoha, Kashiwa, Chiba 277-8581, Japan.
Abstract:
Adsorption states and electronic structure of cyclohexane on clean and hydrogen-saturated Rh(111) surfaces were investigated by scanning tunneling microscopy and photoelectron spectroscopy. Monolayer cyclohexane molecules form an ordered superstructure on the clean Rh(111) surface. The energy level alignment of adsorbed cyclohexane depends on each adsorption site; molecular orbitals of adsorbed cyclohexane on the atop site have lower binding energies than those on the other sites. In contrast, it becomes insensitive to adsorption sites on the hydrogen-saturated Rh(111) surface. By preadsorption of hydrogen, all cyclohexane molecular orbitals are uniformly shifted to lower binding energy compared to those on the clean Rh(111) surface. The observed energy level alignment of cyclohexane on the Rh(111) surfaces is determined by the vacuum level shift and the final-state screening effects.
More Related Videos
Related Concept Videos
Stability of Substituted Cyclohexanes
The two chair conformations of cyclohexanes undergo rapid interconversion at room temperature. Both forms have identical energies and stabilities, each comprising equal amounts of the equilibrium mixture. Replacing a hydrogen atom with a functional group makes the two conformations energetically non-equivalent.
For example, in...
Chair Conformation of Cyclohexane
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this staggered...
Conformations of Cyclohexane
The chair form is the most stable and derives its name from its resemblance to the “easy chair.” In the chair conformation, two carbon atoms are arranged out-of-plane — one above and one below, minimizing the torsional strain. In the chair form, the bond angle is very close to the ideal tetrahedral value,...
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group with both...
Conformations of Cycloalkanes
Cycloaddition Reactions: MO Requirements for Thermal Activation

