Related Experiment Video
Updated: May 14, 2026

Solution-Processed "Silver-Bismuth-Iodine" Ternary Thin Films for Lead-Free Photovoltaic Absorbers
Published on: September 27, 2018
Syntheses, crystal structures and photophysical properties of Ag(I) coordination complexes
Yu-Xian Chi1, Hui-Ping Dai, Shu-Mei Li
1School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, PR China.
Abstract:
Three Ag(I) coordination complexes, [Ag(pyzca)]n (1) (Hpyzca=pyrazine-2-carboxylic acid), Ag[(HNA)(NA)(H2O)4] (2) (HNA=nicotinic acid) and [Ag1Ag2-(2,3-pydc)]n (3) (H2pydc=pyridine-2, 3-dicarboxylic acid) have been synthesized by the hydrothermal method. Their structures are determined by single-crystal X-ray diffractometer. Complex 1 possesses the 3D infinite structure. Complex 2 is a mononuclear coordination complex and exhibits one 3D infinite network by a large number of hydrogen bonds. In complex 3, two crystallographic independent Ag(I) ions exist, i.e., Ag1 is three-coordinate and Ag2 is two-coordinate, forming the 2D layer structure. At room temperature in the solid state, the IR, FP and UV-Vis spectra of all complexes were measured and investigated in detail. The emission and absorption spectra of the three complexes and their corresponding ligands are compared and analyzed.
Related Concept Videos
Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Coordination Number and Geometry
Stereoisomerism
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can be...
Valence Bond Theory
Coordination Compounds and Nomenclature
