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Self-assembly of an asymmetrically functionalized [6]helicene at liquid/solid interfaces

Tatyana Balandina1, Maarten W van der Meijden, Oleksandr Ivasenko

  • 1KU Leuven, Department of Chemistry, Division of Molecular Imaging and Photonics, Celestijnenlaan 200F, B-3001 Heverlee, Belgium.

Chemical Communications (Cambridge, England)
|February 12, 2013
PubMed

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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.