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A sodium manganese ferrocyanide thin film for Na-ion batteries
Tomoyuki Matsuda1, Masamitsu Takachi, Yutaka Moritomo
1Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
Abstract:
A thin film of sodium manganese ferrocyanide, Na1.32Mn[Fe(CN)6]0.83·3.5H2O, exhibits discharge capacity (= 109 mA h g(-1)) and discharge voltage (3.4 V in average) at 0.5 C against Na in aprotic solvent. The ex situ XRD experiments reveal that the host framework remains cubic without showing any structural phase transition during the charge process. The discharge property is discernible up to 40 C.
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