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Published on: September 8, 2017
Index of refraction, density, and solubility of ammonium iodide solutions at high pressure
1Department of Physical and Earth Sciences, Worcester State University, 486 Chandler Street, Worcester, Massachusetts 01602, United States.
Abstract:
An asymmetric moissanite anvil cell is used to study aqueous solutions of ammonium iodide at pressures up to 10 kbar. The index of refraction is measured using the rotating Fabry-Perot technique, with an accuracy of approximately 1%. The mass density and molar volume of the solutions are estimated using the measured index values, and the molar volume is used to predict the pressure dependence of the solubility. The solubility derived from the index of refraction measurements is shown to agree with that which is determined by direct observation of the onset of crystallization.
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