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2-Chloro-benzene-1,4-diaminium bis-(dihydrogenphosphate)
Mohamed Lahbib Mrad1, Matthias Zeller, Mohamed Rzaigui
1Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia.
Abstract:
The asymmetric unit of the title salt, C(6)H(9)ClN(2) (2+)·2H(2)PO(4) (-), contains two dihydrogenphosphate anions and one 2-chloro-benzene-1,4-diaminium dication. The H(2)PO(4) (-) anions are inter-connected through strong O-H⋯O hydrogen bonds to form two-dimensional infinite layers parallel to (001). The organic entities are anchored to the inorganic layers through N-H⋯O hydrogen bonds, and through weak C-Cl⋯O halogen bonds [3.159 (2) Å, 140.48 (7)°]. No π-π stacking inter-actions between neighboring aromatic rings or C-H⋯π inter-actions towards them are observed. Minor disorder is observed for the Cl atom and one hy-droxy group [minor-component occupancy = 3.29 (9)%].
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