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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
3-[2-(5-tert-Butyl-1,2-oxazol-3-yl)hydrazinyl-idene]chroman-2,4-dione
Ahmed Jashari1, Emil Popovski, Bozhana Mikhova
1Group of Physics & Chemistry, Faculty of Natural Sciences & Mathematics, State University of Tetovo, 1200 Tetovo, Macedonia.
Abstract:
In the title compound, C(16)H(15)N(3)O(4), the dihedral angle between the chromane and isoxazole rings [r.m.s. deviations = 0.042 and 0.007 Å, respectively] is 20.33 (12)°. The mol-ecular geometry is stabilized by an intra-molecular N-H⋯O hydrogen bond. In the crystal, N-H⋯O hydrogen bonds generate chains along the c-axis direction. The crystal studied was a non-morohedral twin.
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