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Updated: May 13, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
Model studies of heterogeneous catalytic hydrogenation reactions with gold
Ming Pan1, Adrian J Brush, Zachary D Pozun
1Department of Chemical Engineering, University of Texas at Austin, Austin, TX 78712-0231, USA.
Abstract:
Supported gold nanoparticles have recently been shown to possess intriguing catalytic activity for hydrogenation reactions, particularly for selective hydrogenation reactions. However, fundamental studies that can provide insight into the reaction mechanisms responsible for this activity have been largely lacking. In this tutorial review, we highlight several recent model experiments and theoretical calculations on a well-structured gold surface that provide some insights. In addition to the behavior of hydrogen on a model gold surface, we review the reactivity of hydrogen on a model gold surface in regards to NO2 reduction, chemoselective C=O bond hydrogenation, ether formation, and O-H bond dissociation in water and alcohols. Those studies indicate that atomic hydrogen has a weak interaction with gold surfaces which likely plays a key role in the unique hydrogenative chemistry of classical gold catalysts.
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