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Updated: May 13, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Decametallic Co(II)-cluster-based microporous magnetic framework with a semirigid multicoordinating ligand
Jumei Tian1, Wenliang Li, Bo Li
1Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.
Abstract:
We have synthesized a microporous magnetic framework that contained supertetrahedral decametallic cobalt clusters as nodes and 4-(tris(hydroxymethyl)methyl)pyridine ligands as linkers in a NaCl-like network. This complex shows canted antiferromagnetism with spin-glass behavior. After the removal of the guest molecules, the spin-canting and spin-glass behaviors are maintained. The permanent porosity was evaluated by N2-adsorption measurements. This complex mainly shows a hydrophobic nature, as validated by MeOH- and water-adsorption measurements, which is consistent with the grand canonical Monte Carlo (GCMC) theoretical simulation.
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