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Updated: May 13, 2026

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction
12:22

Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

Published on: February 4, 2013

Recent developments in samarium diiodide promoted organic reactions

Kovuru Gopalaiah1, Henri B Kagan

  • 1Department of Chemistry, University of Delhi, Delhi-110007, India.

Chemical Record (New York, N.Y.)
|March 8, 2013
PubMed
Summary

Samarium diiodide is a versatile reducing agent introduced in the eighties. It facilitates various chemical transformations including bond cleavage, C-C and C-N bond formations, and β-elimination reactions.

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