Related Experiment Video
Updated: May 13, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
(Benzoyl-acetonato-κ(2) O,O')dicarbonyl-rhodium(I)
Carla Pretorius1, Andreas Roodt
1Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.
Abstract:
In the title compound, [Rh(C10H9O2)(CO)2], a distorted square-planar coordination geometry is observed around the Rh(I) atom, formed by the O atoms of the bidentate ligand and two C atoms from the carbonyl ligands. The Rh(I) atom is displaced from the plane through the surrounding atoms by 0.017 Å. In the crystal, C-H⋯O inter-action is observed between a methyl group of the bidentate ligand and a carbonyl O atom. Metallophilic inter-actions [3.308 (3) and 3.461 (3) Å] between neighbouring Rh(I) atoms are encountered in the crystal, resulting in the formation of a metal chain along the b-axis direction.
More Related Videos
10:42Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
10:51The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Related Concept Videos
Reactions at the Benzylic Position: Oxidation and Reduction
Reactions of Aldehydes and Ketones: Baeyer–Villiger Oxidation
The carbonyl center is activated by...
Cyclohexenones via Michael Addition and Aldol Condensation: The Robinson Annulation
Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism
Oxidation of Alkenes: Anti Dihydroxylation with Peroxy Acids
ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3