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Bis(butane-1,4-diammonium) di-μ-oxido-bis[trifluoridooxidomolybdate(V)] monohydrate

J Lhoste¹, A Hemon-Ribaud, V Maisonneuve

¹LUNAM Université, Université du Maine, UMR 6283 CNRS, Institut des Molécules et des Matériaux du Mans, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.

Acta Crystallographica. Section E, Structure Reports Online

|March 8, 2013

Abstract:

The title compound, (C4H14N2)2[Mo2O4F6]·H2O, was obtained by solvothermal reaction at 443 K for 72 h from a mixture of MoO3, HF, 1,4-diamino-butane (dab), water and ethyl-ene glycol. The structure consists of [Mo2O4F6](4-) anionic dimers containing strongly distorted MoO3F3 octa-hedra (with twofold symmetry), diprotonated dab cations and water mol-ecules (twofold symmetry) in the ratio 1:2:1. The cohesion of the three-dimensional structure is ensured through N-H⋯O, N-H⋯F and O-H⋯F inter-actions.

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