Related Experiment Video
Updated: May 13, 2026

Chemical Analysis of Water-accommodated Fractions of Crude Oil Spills Using TIMS-FT-ICR MS
Published on: March 3, 2017
Time course analysis of fractionated thermoxidized virgin olive oil by FTIR spectroscopy
Noelia Tena1, Ramón Aparicio-Ruiz, Diego L García-González
1Instituto de la Grasa (CSIC), Sevilla, Spain.
Abstract:
FTIR spectroscopy has been used to examine the spectral changes taking place in the polar fraction of thermoxidized virgin olive oil and compared to those changes occurring in the neat oil and the nonpolar fraction. It was demonstrated that examination of the polar fraction provides additional and substantially better information of the chemical changes taking place as oxidation proceeds because this fraction concentrates the oxygenated compounds formed. Of particular interest is the enhancement of the OH component of the spectrum (3600-3200 cm(-1)) as well as tertiary alcohol formation (~1167 cm(-1)), including the region associated with epoxides. Time course spectral changes for neat virgin olive oil and its polar and nonpolar fractions are illustrated, compared, and contrasted, demonstrating that the interpretation of neat oil spectra is greatly enhanced by fractionation and may in fact be a preferred means of studying thermoxidation processes.
Related Concept Videos
IR and UV–Vis Spectroscopy of Carboxylic Acids
However, the stretching absorptions for the C=O bond vary depending on the structure of carboxylic acids. The C=O bond of the free carboxylic acids shows a higher stretching frequency, 1760 cm−1, while H-bonded carboxylic acids (dimers) exhibit stretching absorptions at a lower frequency, 1710 cm−1. The C=O bond of the...
Applications of IR Spectroscopy: Overview
IR Spectrometers
IR Frequency Region: Fingerprint Region
The...
IR Spectroscopy: Molecular Vibration Overview
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview
The ATR process begins by directing a beam...

