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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Tetra-kis[μ-2-(meth-oxy-carbon-yl)benzoato-κ(2) O (1):O (1')]bis-[(acetonitrile-κN)copper(II)](Cu-Cu)
Jing-Lin Wang1, Cai-Rong Wang, Zhi-Jun Wang
1Department of Chemistry, Changzhi University, Changzhi, Shanxi 046011, People's Republic of China.
Abstract:
In the binuclear copper(II) title complex, [Cu2(C9H7O4)4(C2H3N)2], an inversion centre is situtated at the mid-point of the Cu-Cu bond. The Cu(II) atom together with its four coordinated O atoms are in a distorted planar square arrangement while the nitro-gen and the other Cu(II) atom are located in apical positions. The whole mol-ecule looks like a paddle-wheel. In the crystal, chains are assembled along the b axis through C-H⋯O hydrogen bonds and slipped π-π inter-actions between the benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.6929 (3) Å and slippage = 0.641 (1) Å].
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