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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
1-(5-Bromo-2-chloro-phen-yl)-2,2-di-chloro-1-(4-eth-oxy-phen-yl)cyclo-propane
Shuwen Han1, Yongheng Shi, Wang Yuli
1Graduate School, Tianjin University of Traditional Chinese Medicine, Tianjin 300193, People's Republic of China ; Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin 300193, People's Republic of China.
Abstract:
The asymmetric unit of the title compound, C17H14BrCl3O, contains two independent mol-ecules with different dihedral angles between the benzene rings [79.2 (1) and 72.7 (1)°]. In the crystal, weak C-H⋯π inter-actions link mol-ecules related by translation along the b axis into two crystallographically independent chains.
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