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Imaging the effects of bend-excitation in the F + CD4(vb=0,1) → DF(v) + CD3(v2=1,2) reactions
1Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica , P.O. Box 23-166, Taipei, Taiwan 10617.
Abstract:
The title reaction was studied over the collisional energy range 0.9-4.0 kcal mol(-1), using a time-sliced velocity-imaging technique in a crossed-beam experiment. Both the integral and differential cross sections were measured in a product pair-correlation manner. Experimental evidence for the dual reaction mechanisms, a direct abstraction and a resonance-mediated pathway, were presented and await future theoretical confirmation.
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