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Synthesis and functionalization of [60]fullerene-fused imidazolines
Cheng-Lin He1, Rui Liu, Dan-Dan Li
1CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, PR China.
Abstract:
The silver carbonate promoted reaction of [60]fullerene with (Z)-N-arylbenzamidines afforded the unprecedented C60-fused imidazoline derivatives in high yields. Substrates with both electron-donating and -withdrawing groups on aromatic rings could be employed. In addition, the electrochemistry and further selective functionalization of the obtained C60-fused imidazolines were investigated.
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