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Updated: May 13, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Two birds with one stone: anion templated ball-shaped Ag56 and disc-like Ag20 clusters
Di Sun1, Hua Wang, Hai-Feng Lu
1Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, People's Republic of China. dsun@sdu.edu.cn
Abstract:
One-pot reaction of AgSBu(t) and AgOAc in the methanol-ethanol-DMF solvent system under room temperature gave a ball-shaped Ag56 cluster and a disc-like Ag20 cluster. The formations of clusters and are templated by an in situ generated S(2-) ion from the cleavage of the S-C bond of SBu(t) and CO3(2-) ion from the fixation of atmospheric carbon dioxide, respectively. Interestingly, cluster 1 only emits bright-red light in the solid state at 77 K and is not emissive at room temperature.
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