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On the use of amine-borane complexes to synthesize iron nanoparticles

Frédéric Pelletier1, Diana Ciuculescu, Jean-Gabriel Mattei

  • 1CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, 31077 Toulouse, France.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|March 21, 2013
PubMed

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
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