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Biological activity of Pd(II) complexes with mono- and disubstituted pyridines--experimental and theoretical studies

Agnieszka Krogul1, Jakub Cedrowski, Katarzyna Wiktorska

  • 1Faculty of Chemistry, University of Warsaw, Pasteura 1, 02-093 Warsaw, Poland. akrogul@chem.uw.edu.pl

Bioorganic & Medicinal Chemistry Letters
|March 22, 2013
PubMed

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Heterocyclic amines, where the N atom is a part of an alicyclic system, are similar in basicity to alkylamines. Interestingly, the heterocyclic amine having a nitrogen atom as part of an aromatic ring has much less basicity than its corresponding alicyclic counterpart. For this reason, as presented in Figure 1, piperidine (pKb = 2.8) is significantly more basic than pyridine (pKb = 8.8).