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A potential rhodium cancer therapy: studies of a cytotoxic organorhodium(I) complex that binds DNA

Jeanette R McConnell1, Dimple P Rananaware, Deborah M Ramsey

  • 1Department of Chemistry, University of New South Wales, Kensington, NSW 2052, Australia.

Bioorganic & Medicinal Chemistry Letters
|April 2, 2013
PubMed

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The mitochondrial electron transport chain (ETC) is the main energy generation system in the eukaryotic cells. However, mitochondria also produce cytotoxic reactive oxygen species (ROS) due to the large electron flow during oxidative phosphorylation. While Complex I is one of the primary sources of superoxide radicals, ROS production by Complex II is uncommon and may only be observed in cancer cells with mutated complexes.
ROS generation is regulated and maintained at moderate levels necessary...