Rheological study of two-dimensional very anisometric colloidal particle suspensions: from shear-induced orientation...

In the present study, we investigate the evolution with shear of the viscosity of aqueous suspensions of size-selected natural swelling clay minerals for volume fractions extending from isotropic liquids to weak nematic gels. Such suspensions are strongly shear-thinning, a feature that is systematically observed for suspensions of nonspherical particles and that is linked to their orientational properties. We then combined our rheological measurements with small-angle X-ray scattering experiments that, after appropriate treatment, provide the orientational field of the particles. Whatever the clay nature, particle size, and volume fraction, this orientational field was shown to depend only on a nondimensional Péclet number (Pe) defined for one isolated particle as the ratio between hydrodynamic energy and Brownian thermal energy. The measured orientational fields were then directly compared to those obtained for infinitely thin disks through a numerical computation of the Fokker-Plank equation. Even in cases where multiple hydrodynamic interactions dominate, qualitative agreement between both orientational fields is observed, especially at high Péclet number. We have then used an effective approach to assess the viscosity of these suspensions through the definition of an effective volume fraction. Using such an approach, we have been able to transform the relationship between viscosity and volume fraction (ηr = f(φ)) into a relationship that links viscosity with both flow and volume fraction (ηr = f(φ, Pe)).