Cucurbit[7]uril as a "protective agent": controlling photochemistry and detecting 1-adamantanamine
Hui Yang1, Yiliu Liu, Liulin Yang
1Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, PR China.
Abstract:
Cucurbit[7]uril (CB[7]) as a "protective agent" can effectively inhibit the [4+4] photochemical reaction of 1,1'-(butane-1,4-diyl)bis(2-aminopyridine)bromide (DPAD) by host-guest interaction between CB[7] and DPAD. In addition, the host-guest complex DPAD-CB[7] as a supramolecular sensor can detect the concentration of 1-adamantanamine with good sensitivity and selectivity because of the guest competitive complexation.
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