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Updated: May 12, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Chiral induction and amplification in supramolecular systems at the liquid-solid interface
Hong Xu1, Elke Ghijsens, Subi J George
1Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven-University of Leuven, Celestijnenlaan 200 F, B-3001, Leuven, Belgium.
Abstract:
Chiral induction and amplification in surface-confined supramolecular monolayers are investigated at the liquid-solid interface. Scanning tunneling microscopy (STM) proves that achiral molecules can self-assemble into globally chiral patterns through a variety of approaches, including induction by chiral solvents or by a novel chiral amplification method. Our study demonstrates the aptness of both approaches, which have already been applied to (supramolecular) polymers in solution, to create chiral supramolecular monolayers at the liquid-solid interface.
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