Extended potential-gradient architecture of a phenylazomethine dendrimer

A dendritic nanoshell based on rigid phenylazomethine units was synthesized up to fifth generation around a zinc porphyrin core. Due to the finely organized sparse architecture, accessibility to the core can be discriminated by the size of the molecules and ionic species. By using this function, the lifetime of the photochemically produced radical ion pair can be extended over 200 times longer along with a good quantum yield.