Spectroscopic studies and molecular orbital calculations on the charge transfer reaction between DDQ and
Khairia M Al-Ahmary1, Moustafa M El-Kholy, Iman A Al-Solmy
1Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia.
Abstract:
Charge transfer complex formation between 2-aminopyridine (donor, 2AP) with 2,3-dichloro-5,6-dicyano-p-benzoquinone (acceptor, DDQ) has been studied spectrophotometrically in acetonitrile (CH3CN). The newly formed CT-complex has reddish brown color and is characterized by the appearance of new absorption bands in the 375-650 nm regions where acceptor and donor do not have any absorption. Maximum and constant absorbance of the complex was obtained after 10 min at 20 °C with 1 mL 5×10(-3) M DDQ in CH3CN. Based on photometric titration method, the stoichiometry of the formed CT-complex was found to be 1:1 [(2AP)(DDQ)]. Minimum-maximum absorbances method has been applied to estimate the formation constant of the complex where it recorded large value confirming its high stability. Molecular orbital calculations utilizing GAMESS computations were carried out in order to record changes in the electronic structure and molecular geometry of the formed CT-complex. In addition, the infrared vibrational frequencies of the complex were computed and compared with experimental results.
Related Concept Videos
Aryldiazonium Salts to Azo Dyes: Diazo Coupling
Diazonium Group Substitution: –OH and –H
¹³C NMR: Distortionless Enhancement by Polarization Transfer (DEPT)
Basicity of Heterocyclic Aromatic Amines
NMR Spectroscopy Of Amines
1° Amines to Diazonium or Aryldiazonium Salts: Diazotization with NaNO2 Mechanism


