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Updated: May 12, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Growth and characterization of semi-organic nonlinear optical crystal: sodium 2,4-dinitrophenolate monohydrate
L Guru Prasad1, V Krishnakumar, R Nagalakshmi
1Department of Physics, Periyar University, Salem 636 011, India.
Abstract:
Sodium 2,4-dinitrophenolate monohydrate salt has been synthesized and the crystals have been grown in aqueous solution by slow evaporation solution growth technique. Grown crystal was confirmed by powder XRD studies. Functional groups presented in the grown crystal were identified and their vibrational properties were studied by recording FTIR spectrum. Thermal stability of the grown crystal was deliberated by recording TGA/DTA. Existence of the ionic form in the crystal was confirmed and the energy gap of the crystal was also calculated by analyzing UV-VIS-NIR spectrum. Second harmonic frequency generation was examined by Kurtz and Perry powder test and it reveals that the relative conversion efficiency was 2.5 times greater than the urea. Theoretical first order hyperpolarizability value was calculated for the optimized structure.
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