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Related Concept Videos

Imperfections in Crystal Structure: Point, Line and Plane Defects01:25

Imperfections in Crystal Structure: Point, Line and Plane Defects

A perfect crystal, in theory, has a uniform structure with the same unit cell and lattice points throughout. However, any deviation from this periodic arrangement is known as an imperfection or defect. These defects can be categorized into three types: point, line, and plane defects.Point defects occur when there is a deviation from the ideal due to missing atoms, displaced atoms, or additional atoms. These imperfections might occur due to imperfect packing during crystallization or because of...
Liquid–Solid Solutions01:29

Liquid–Solid Solutions

The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...
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Two Components: Liquid–Liquid Systems

A pressure-composition phase diagram explicitly describes the behavior of an ideal solution of two volatile liquids under varying pressures and compositions. A pressure-composition diagram has two main curves. The bubble point curve represents the plot of pressure versus liquid mole fraction. It indicates the pressure at which the first bubble of vapor forms from the liquid phase as the system pressure decreases.The dew point curve is the pressure versus vapor mole fraction. It indicates the...
Structures of Solids02:22

Structures of Solids

Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
Imperfections in Crystal Structure: Stoichiometric Point Defects01:26

Imperfections in Crystal Structure: Stoichiometric Point Defects

Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...
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Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...

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Updated: May 12, 2026

Nanoscale Characterization of Liquid-Solid Interfaces by Coupling Cryo-Focused Ion Beam Milling with Scanning Electron Microscopy and Spectroscopy
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Nanoscale Characterization of Liquid-Solid Interfaces by Coupling Cryo-Focused Ion Beam Milling with Scanning Electron Microscopy and Spectroscopy

Published on: July 14, 2022

Two-dimensional crystal engineering at the liquid-solid interface.

Shuhei Furukawa1, Steven De Feyter

  • 1Division of Molecular and Nano Materials, Department of Chemistry, and INPAC -Institute for Nanoscale Physics and Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium.

Topics in Current Chemistry
|April 23, 2013
PubMed
Summary
This summary is machine-generated.

This review explores two-dimensional crystal engineering at liquid-solid interfaces. It highlights challenges and successes in creating ordered molecular patterns for advanced applications.

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Fabricating van der Waals Heterostructures with Precise Rotational Alignment
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Fabricating van der Waals Heterostructures with Precise Rotational Alignment

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Last Updated: May 12, 2026

Nanoscale Characterization of Liquid-Solid Interfaces by Coupling Cryo-Focused Ion Beam Milling with Scanning Electron Microscopy and Spectroscopy
11:03

Nanoscale Characterization of Liquid-Solid Interfaces by Coupling Cryo-Focused Ion Beam Milling with Scanning Electron Microscopy and Spectroscopy

Published on: July 14, 2022

Fabricating van der Waals Heterostructures with Precise Rotational Alignment
09:25

Fabricating van der Waals Heterostructures with Precise Rotational Alignment

Published on: July 5, 2019

Area of Science:

  • Supramolecular chemistry
  • Surface science
  • Materials science

Background:

  • Three-dimensional crystal engineering is established.
  • Scanning tunneling microscopy enables 2D exploration.
  • Supramolecular chemistry tools are applied to surfaces.

Purpose of the Study:

  • To review efforts in 2D crystal engineering at liquid-solid interfaces.
  • To discuss challenges in designing self-assembling molecules.
  • To cover the formation of 2D porous networks and multicomponent systems.

Main Methods:

  • Utilizing supramolecular chemistry principles.
  • Leveraging scanning tunneling microscopy for submolecular resolution.
  • Investigating molecule-molecule, molecule-substrate, and solvent-substrate interactions.

Main Results:

  • Progress in achieving 2D crystal engineering at the liquid-solid interface.
  • Demonstration of self-assembly into targeted patterns.
  • Formation of 2D porous networks and multicomponent systems.

Conclusions:

  • 2D crystal engineering at liquid-solid interfaces is advancing.
  • Overcoming interaction complexities is key to molecular design.
  • Applications span molecular electronics to surface reactivity.