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Updated: May 11, 2026
Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Ionothermal synthesis of chiral metal phosphite open frameworks with in situ generated organic templates
Li-Ming Li1, Kai Cheng, Fei Wang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
Abstract:
Two novel three-dimensional chiral metal phosphite open frameworks with 4-connected quartz topology, [Me2-DABCO][M2(HPO3)3] [M = Co (1), Zn (2); Me2-DABCO = N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane], have been ionothermally synthesized in deep eutectic solvents (choline chloride/1,3-dimethylurea). It is interesting that the organic template, Me2-DABCO, is in situ generated from the alkylation reaction of 1,4-diazabicyclo[2.2.2]octane and dimethyl phosphites.
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