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Preparation of N-(2-alkoxyvinyl)sulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
Published on: January 3, 2018
o-Phenyl-enediaminium chloride nitrate.
Sarra Soudani1, Riadh Kefi, Christian Jelsch
1Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia.
Summary
This study details the crystal structure of a molecular salt, C6H10N2(2+)·NO3(-)·Cl(-). It reveals how symmetry elements and hydrogen bonds create a layered structure with a 3D network.
Area of Science:
- Crystallography
- Materials Science
- Chemical Physics
Background:
- Understanding molecular salt structures is crucial for designing new materials.
- Crystal symmetry and intermolecular interactions dictate material properties.
Purpose of the Study:
- To elucidate the crystal structure of the molecular salt C6H10N2(2+)·NO3(-)·Cl(-).
- To analyze the role of symmetry elements and hydrogen bonding in the crystal packing.
Main Methods:
- Single-crystal X-ray diffraction was used to determine the crystal structure.
- Analysis of crystallographic symmetry operations (mirror planes).
- Identification and analysis of hydrogen bonding networks (N-H⋯Cl, N-H⋯(N,O), C-H⋯O).
Main Results:
- The cation C6H10N2(2+) is generated by a crystallographic mirror plane.
- Nitrate and chloride ions also lie on reflection planes.
- Hydrogen bonds form (001) layers, with benzene rings in inter-layer regions.
- Weak C-H⋯O bonds link layers into a 3D network.
Conclusions:
- The crystal structure is characterized by symmetry-driven molecular arrangements.
- Hydrogen bonding plays a key role in forming a layered and subsequently a three-dimensional network.
- This detailed structural analysis provides a foundation for understanding the physical and chemical properties of this molecular salt.
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