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A terthiophene-containing alkynylplatinum terpyridine Pacman complex: controllable folding/unfolding modulated by
Yang Cao1, Michael O Wolf, Brian O Patrick
1Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Z1, Canada.
Abstract:
Folded and unfolded solid-state structures of a bimetallic alkynylplatinum terpyridine complex with a flexible terthiophene linker have been obtained. Weak intermolecular interactions including π-π stacking and C-H···O and C-H···Cl interactions as well as Cl-π interactions stabilize the folded structure. In solution, folding is studied by electronic absorption spectroscopy and (1)H and NOESY NMR experiments.
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