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Comparative study of processing methods for starch/gelatin films.

Farayde M Fakhouri1, Daryne Costa, Fábio Yamashita

  • 1School of Chemical Engineering, Department of Polymer Technology, State University of Campinas, UNICAMP, P.O. Box 6066, 13083-970 Campinas, SP, Brazil. farayde@yahoo.com.br

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|May 8, 2013
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Processing methods significantly impact bioplastic properties. Casting produced superior starch/gelatin films with better transparency and lower water vapor permeability (WVP) compared to pressing or blowing techniques.

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Area of Science:

  • Materials Science
  • Polymer Science
  • Food Science

Background:

  • Starch/gelatin films are promising biodegradable materials.
  • Glycerol and sorbitol are common plasticizers used to improve film flexibility.
  • Optimizing processing methods is crucial for enhancing bioplastic performance.

Purpose of the Study:

  • To investigate the effect of four different processing methods on the properties of starch/gelatin films.
  • To compare the performance of films produced by casting, pressing, pressing followed by blowing, and extrusion followed by blowing.
  • To identify optimal processing conditions for enhanced film characteristics.

Main Methods:

  • Four processing techniques were employed: casting, pressing, pressing followed by blowing, and extrusion followed by blowing.
  • Films were characterized for properties such as homogeneity, transparency, opacity, water vapor permeability (WVP), and tensile strength (TS).
  • Crystallinity was analyzed using thermal analysis and X-ray diffraction.

Main Results:

  • Cast films exhibited superior homogeneity and transparency with lower opacity and WVP compared to other methods.
  • Films with 3% lipophilic starch and sorbitol, processed by casting, showed the lowest WVP and highest TS.
  • Films processed by pressing and blowing displayed surface cracks, low TS, and high WVP, and were the only ones to exhibit crystallinity.

Conclusions:

  • Processing technique is a critical factor influencing the physical and mechanical properties of starch/gelatin bioplastics.
  • Casting is the most effective method for producing high-quality starch/gelatin films with desirable properties.
  • Further research can focus on tailoring processing parameters to achieve specific film functionalities for various applications.