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Related Concept Videos

Carrier Transport01:21

Carrier Transport

The generation of electrical current in semiconductors is fundamentally driven by two mechanisms: drift and diffusion. These processes are essential for the functionality and performance of semiconductor-based devices.
Drift Current:
The drift of charge carriers is started by an external electric field (E). Charged particles, such as electrons and holes, experience an acceleration between collisions with lattice atoms. For electrons, this results in a drift velocity (vd) given by:
Facilitated Transport01:19

Facilitated Transport

The chemical and physical properties of plasma membranes cause them to be selectively permeable. Since plasma membranes have both hydrophobic and hydrophilic regions, substances need to be able to transverse both regions. The hydrophobic area of membranes repels substances such as charged ions. Therefore, such substances need special membrane proteins to cross a membrane successfully. In  facilitated transport, also known as facilitated diffusion, molecules and ions travel across a membrane via...
Facilitated Transport01:19

Facilitated Transport

The chemical and physical properties of plasma membranes cause them to be selectively permeable. Since plasma membranes have both hydrophobic and hydrophilic regions, substances need to be able to transverse both regions. The hydrophobic area of membranes repels substances such as charged ions. Therefore, such substances need special membrane proteins to cross a membrane successfully. In  facilitated transport, also known as facilitated diffusion, molecules and ions travel across a membrane via...
Facilitated Transport01:19

Facilitated Transport

The chemical and physical properties of plasma membranes cause them to be selectively permeable. Since plasma membranes have both hydrophobic and hydrophilic regions, substances need to be able to transverse both regions. The hydrophobic area of membranes repels substances such as charged ions. Therefore, such substances need special membrane proteins to cross a membrane successfully. In  facilitated transport, also known as facilitated diffusion, molecules and ions travel across a membrane via...
Debye–Huckel–Onsager Conductance Equation01:28

Debye–Huckel–Onsager Conductance Equation

The Debye-Hückel-Onsager equation is a cornerstone of physical chemistry, providing a method to determine the molar conductance (Λm) and molar conductance at infinite dilution (Λ°m) for uni-univalent electrolytes.Uni-univalent electrolytes are electrolytes that dissociate in solution to produce one cation with a +1 charge and one anion with a –1 charge per formula unit.This equation addresses two crucial phenomena: the asymmetry effect and the electrophoretic effect. According to this equation,...
Transport Number01:31

Transport Number

The transport number is the fraction of the total current carried by an ion in an electrolyte solution. It is defined as the ratio of the current carried by a specific ion to the total current flowing through the solution. The transport number, t, is central to understanding ionic mobility, which describes how fast an ion moves under the influence of an electric field. This link connects the physical behavior of ions in solution to the chemical processes that occur during electrochemical...

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Related Experiment Video

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Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform
05:39

Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform

Published on: August 2, 2019

Quantum transport with two interacting conduction channels.

Alexander J White1, Agostino Migliore, Michael Galperin

  • 1Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, California 92093, USA.

The Journal of Chemical Physics
|May 10, 2013
PubMed
Summary
This summary is machine-generated.

This study investigates transport properties in coupled quantum channels. An approximate method accurately predicts steady-state current, except near the charging threshold, crucial for understanding molecular junctions.

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Area of Science:

  • Condensed Matter Physics
  • Quantum Transport

Background:

  • Investigates conduction junction models with two coupled channels differing in lead couplings.
  • Relevant to molecular redox junctions and electron counting devices.

Purpose of the Study:

  • Analyze transport properties of a specific two-channel conduction junction model.
  • Compare full quantum calculations with approximate mixed quantum-classical methods.

Main Methods:

  • Utilized the pseudoparticle non-equilibrium Green function method for full quantum calculations.
  • Employed an approximate mixed quantum-classical approach considering averaged rates or energy for inter-channel correlations.

Main Results:

  • The averaged rates approximation accurately predicts steady-state current across most voltage regimes.
  • Significant deviations observed only at the charging threshold of the weakly coupled level.
  • These deviations are critical for modeling negative differential conductance in molecular junctions.

Conclusions:

  • The averaged rates approximation is generally reliable for steady-state current calculations.
  • Accurate modeling of negative differential conductance requires careful consideration of deviations near the charging threshold.