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Solid state structure of Bi(N3)3, Bi(N3)3·solvates and the structural dynamics in the [Bi(N3)6]3- anion

Kati Rosenstengel1, Axel Schulz, Alexander Villinger

  • 1Abteilung Anorganische Chemie, Institut für Chemie, Universität Rostock, Albert-Einstein-Strasse 3a, 18059 Rostock, Germany.

Inorganic Chemistry
|May 11, 2013
PubMed
Summary

Pure bismuth triazide, a highly explosive compound, was synthesized using bismuth trifluoride and trimethylsilyl azide under specific solvothermal conditions. Solvent choice significantly impacts azide product purity, with further studies on structural dynamics and ligand exchange reactions.

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